Section 11 of 14

Thermal Transformation

Heat · Precision · Purpose

Seven stages of heat application in Buna processing — from enzymatic transformation at ambient temperature to the outer boundary of thermal development.

Thermal Transformation

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Process — Shaping the Leaf Index Flavour & Aroma
Citane Context — Thumpassery Estate

Citane processing at Thumpassery uses oven drying at 70°C as the standard research baseline. Pan roasting and smoke drying are documented in the Kuti and Kawa Daun traditions. Thermal precision is one of the areas where Citane is actively developing its own framework.

Seven Stages of Heat Application
Ambient / No Heat
Stage 01 — Cool

The leaf is worked without applied heat. Enzymatic activity is active. Withering, rolling, and fermentation all occur in this stage. Enzymatic action is the primary transformation force.

See Withering →Research
Low Heat 40–70°C
Stage 02 — Gentle

Gentle warming. Begins to slow enzymatic activity without fully arresting it. Used for controlled drying of fermented styles and some white-style preparations.

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Enzyme Arrest 70–85°C
Stage 03 — Stabilise

The temperature range at which polyphenol oxidase (PPO) is denatured and enzymatic oxidation ceases. The leaf is locked in its current chemical state. This stage is used to produce green-style Buna.

None →
Drying 85–100°C
Stage 04 — Reduce

Extended moisture reduction without deep thermal transformation. Stabilises the leaf for storage. Standard oven drying temperature in published Buna research (Fibrianto et al. 2025).

None →
Light Thermal 100–140°C
Stage 05 — Develop

Maillard reactions begin above approximately 120°C. Amino acids and reducing sugars interact to produce toasted, nutty, and caramel character. The first stage of deliberate flavour development by heat.

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Medium Thermal 140–170°C
Stage 06 — Deepen

Trigonelline begins to degrade, contributing pyridine notes. CGA lactone formation adds structured bitterness distinct from raw CGA. Roasted character develops. Pyrazines emerge at trace levels (Steger et al. 2022).

None →
Char / Toast 170°C+
Stage 07 — Boundary

The outer limit of useful thermal transformation. Beyond this, compounds degrade rather than develop. A useful marker — the boundary between deliberate roasting and damage.

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A Buna-Native Principle — Not Tea Logic

In extended wet heat (decoction), perceived sweetness may increase and perceived bitterness may decrease as decoction time extends. This pattern is the opposite of what happens when Camellia sinensis tea is over-steeped. Published brewing optimisation research (Fibrianto et al. 2024) supports this direction of effect, though the precise mechanism and the conditions under which it applies require further study. It should not be stated as a universal law — it is a documented pattern in specific preparations.

Kill-Green
Technique

Rapid heat application to arrest enzymatic activity and preserve the leaf in a green state. The Buna equivalent of Japanese steam-fixation in green tea. Speed matters — delay allows oxidation to begin.

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Pan Roasting
Technique

Dry-heat roasting in a flat pan. Surface contact and flip-based technique. Used in Kuti tradition for the flat-pan preparation. Creates even surface browning without charring.

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Smoke Drying
Technique

Simultaneous drying and smoke infusion. Kawa Daun tradition. Cinnamon wood creates a distinctive aromatic signature in the dried leaf through volatile compound absorption.

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Oven Drying
Technique

Controlled temperature drying. Research standard (70°C / 4 hours in Steger et al. 2022 and Fibrianto et al. 2025). Consistent enzyme arrest and volatile retention.

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Connected sections
Process — Shaping the Leaf Index Flavour & Aroma